Channel: Oxygenases

An oxygenase is any enzyme that oxidizes a substrate by transferring the oxygen from molecular oxygen O2 (as in air) to it. The oxygenases form a class of oxidoreductases; their EC number is EC 1.13 or EC 1.14. Wikipedia (CC BY-SA 3.0)

2023 Articles

263 articles

Synergistic Binding of the Halide and Cationic Prime Substrate of l-Lysine 4-Chlorinase, BesD, in Both Ferrous and Ferryl States

  • Jeffrey W Slater, Chi-Yun Lin, Monica E Neugebauer, …, Alexey Silakov, Carsten Krebs, J Martin Bollinger
  • Biochemistry, 10.1021/acs.biochem.3c00248
Comment Section

Coordination Dynamics of Iron is a Key Player in the Catalysis of Non-heme Enzymes

Comment Section

Nuclear Resonance Vibrational Spectroscopy Definition of Peroxy Intermediates in Catechol Dioxygenases: Factors that Determine Extra- versus Intradiol Cleavage

  • Jeffrey T Babicz, Melanie S Rogers, Dory E DeWeese, …, Makoto Seto, John D Lipscomb, Edward I Solomon
  • J Am Chem Soc, 10.1021/jacs.3c02242
Comment Section

Solvent isotope effects in the catalytic cycle of P450 CYP17A1: Computational modeling of the hydroxylation and lyase reactions

  • Ilia G Denisov, Stephen G Sligar, Ilia G Denisov, …, Stephen G Sligar, Ilia G Denisov, Stephen G Sligar
  • J Inorg Biochem, 10.1016/j.jinorgbio.2023.112202
Comment Section

Elusive Active Intermediates and Reaction Mechanisms of ortho-/ipso-Hydroxylation of Benzoic Acid by Hydrogen Peroxide Mediated by Bioinspired Iron(II) Catalysts

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A human protein hydroxylase that accepts D-residues

  • Hwanho Choi, Adam P Hardy, Thomas M Leissing, …, Michael A McDonough, Hwangseo Park, Christopher J Schofield
  • None, 10.1038/s42004-020-0290-5
Comment Section

Reactivity Differences of Trigonal Pyramidal Nonheme Iron(IV)-Oxo and Iron(III)-Oxo Complexes: Experiment and Theory

  • Yuanxin Cao, Juan A Valdez-Moreira, Sam Hay, …, Sam Hay, Jeremy M Smith, Sam P de Visser
  • Chemistry, 10.1002/chem.202300271
Comment Section

Dynamic Domain Links Substrate Binding and Catalysis in the Factor-Inhibiting-HIF-1

  • Cristina B Martin, Cornelius Y Taabazuing, Michael J Knapp, Cristina B Martin, Cornelius Y Taabazuing, Michael J Knapp
  • Biochemistry, 10.1021/acs.biochem.3c00231
Comment Section

Repurposing Iron- and 2-Oxoglutarate-Dependent Oxygenases to Catalyze Olefin Hydration

  • Bingnan Wang, Yong Lu, Lide Cha, …, Yisong Guo, Wei-Chen Chang, Chuo Chen
  • Angew Chem Int Ed Engl, 10.1002/anie.202311099
Comment Section

2022 Articles

15 articles

Mechanistic Insight into Peptidyl-Cysteine Oxidation by the Copper-Dependent Formylglycine-Generating Enzyme

  • Yao Wu, Cong Zhao, Yanzhuang Su, …, Yanzhuang Su, Sason Shaik, Wenzhen Lai
  • Angew Chem Int Ed Engl, 10.1002/anie.202212053
Comment Section

Contrasting Mechanisms of Aromatic and Aryl-Methyl Substituent Hydroxylation by the Rieske Monooxygenase Salicylate 5-Hydroxylase

  • Melanie S Rogers, Adrian M Gordon, Todd M Rappe, …, Todd M Rappe, Jason D Goodpaster, John D Lipscomb
  • Biochemistry, 10.1021/acs.biochem.2c00610
Comment Section

A Compound I Mimic Reveals the Transient Active Species of a Cytochrome P450 Enzyme: Insight into the Stereoselectivity of P450-Catalysed Oxidations

  • Kazuto Suzuki, Joshua Kyle Stanfield, Keita Omura, …, Yuichiro Aiba, Hiroshi Sugimoto, Osami Shoji
  • Angew Chem Int Ed Engl, 10.1002/anie.202215706
Comment Section

Bio-inspired Cu(II) amido-quinoline complexes as catalysts for aromatic C-H bond hydroxylation

  • Monika, Aniruddha Sarkar, Naiwrit Karmodak, …, Naiwrit Karmodak, Basab Bijayi Dhar, Sanjay Adhikari
  • Dalton Trans, 10.1039/d2dt03242b
Comment Section

H2O2-Driven Hydroxylation of Steroids Catalyzed by Cytochrome P450 CYP105D18: Exploration of the Substrate Access Channel

  • Bashu Dev Pardhe, Kyoung Pyo Kwon, Jong Kook Park, …, Jong Kook Park, Jun Hyuck Lee, Tae-Jin Oh
  • Appl Environ Microbiol, 10.1128/aem.01585-22
Comment Section

Comparative oxidative ability of mononuclear and dinuclear high-valent iron-oxo species towards the activation of methane: does the axial/bridge atom modulate the reactivity?

  • Mursaleem Ansari, Mursaleem Ansari, Mursaleem Ansari, Gopalan Rajaraman
  • Dalton Trans, 10.1039/d2dt02559k
Comment Section

Enantioselective Single and Dual α-C-H Bond Functionalization of Cyclic Amines via Enzymatic Carbene Transfer

  • Xinkun Ren, Bo M Couture, Ningyu Liu, …, Manjinder S Lall, Jeffrey T Kohrt, Rudi Fasan
  • J Am Chem Soc, 10.1021/jacs.2c10775
Comment Section

Insight into Different Stages of Steroid Degradation in Thermophilic Saccharopolyspora hirsuta VKM Ac-666T Strain

  • Tatyana Lobastova, Victoria Fokina, Irina Pozdnyakova-Filatova, …, Sergey Tarlachkov, Andrey Shutov, Marina Donova
  • Int J Mol Sci, 10.3390/ijms232416174
Comment Section

Inclusion of the in-chain sulfur in 3-thiaCTU increases the efficiency of mitochondrial targeting and cell killing by anticancer aryl-urea fatty acids

  • Md Khalilur Rahman, Balasubrahmanyam Umashankar, Hassan Choucair, …, Colin R Dunstan, Tristan Rawling, Michael Murray
  • Eur J Pharmacol, 10.1016/j.ejphar.2022.175470
Comment Section

Zn(II)-Catalyzed Selective N-Alkylation of Amines with Alcohols Using Redox Noninnocent Azo-Aromatic Ligand as Electron and Hydrogen Reservoir

  • Subhajit Chakraborty, Rakesh Mondal, Subhasree Pal, …, Amit Kumar Guin, Lisa Roy, Nanda D Paul
  • J Org Chem, 10.1021/acs.joc.2c01773
Comment Section